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Crystal Records of the Origin, Evolution, and Thermal Histories of Magmas

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Title Crystal Records of the Origin, Evolution, and Thermal Histories of Magmas
Names Bradshaw, Richard W., 1985- (creator)
Kent, Adam J.R. (advisor)
Date Issued 2017-02-14 (iso8601)
Note Graduation date: 2017
Abstract In volcanic systems, magma is generally stored in the shallow crust prior to
eruption. The conditions of this storage directly impact whether the magma
eventually erupts, or crystallizes within the crust to form a pluton. In this dissertation
I present four studies that investigate the storage conditions of a number of volcanic
systems and their timescales. A widespread method to quantify the timescales of
magmatic processes is diffusion modeling of compositional variations in zoned
crystals. Obtaining timescale information from diffusion modeling relies on fitting
modeled diffusion profiles to measured compositional gradients. Therefore, the
spatial resolution of the geochemical analysis technique used to characterize these
gradients has the potential to limit the accuracy and precision of calculated diffusion
timescales, especially when the resolution of the individual analyses approaches the
width of the observed diffusion gradient. A probabilistic modeling approach is
presented to assess the accuracy of short diffusion timescale estimates with respect to
the spatial resolution of the geochemical measurement of compositional zoning. We
develop a generalized method to quantify these shortest timescales that can be
accurately calculated for given spatial resolutions and diffusivity. This provides a
simple method to assess the accuracy of short diffusion timescales.
Olivine-rich picrites are a relatively common eruptive product of ocean island
and flood basalt volcanism. This rock type has a primitive bulk-rock composition
similar to mantle-derived melts; however, picrites are olivine-rich. The common
interpretation for the formation of picrites is the accumulation of olivine in more
evolved, basaltic liquids. Many picrites contain two textural populations of olivine,
one with deformation features (kink bands, subgrains or undulose extinction), and one
without deformation. Deformation textures in olivine is traditionally thought to form
by plastic deformation during storage in a deforming cumulate zone. However,
recently it has been proposed that deformation textures could be the result of growth
phenomena. We use textural (crystal sizes, deformation textures and minor element
zoning patterns) and geochemical analysis (trace element compositions and minor
element diffusion) of olivine from the 1959 eruption of Kīlauea Iki to show that these
two olivine populations are derived from different sources and that the deformed
population experienced longer residence times than the undeformed population. Our
results are consistent with the interpretation that olivine is deformed in cumulate
zones, and later entrained in unrelated magmas.
The conditions of upper crustal magma storage in arc settings are
fundamentally important to the evolution and ultimate fate of arc magmas. Current
thermal models suggest that accumulation of significant bodies of eruptible magma
require either high magma influx and storage at elevated temperatures, or lower flux
and storage as low temperature crystal mushes that are later thermally rejuvenated.
We use textural (crystal sizes) and geochemical (plagioclase trace elements and trace
element diffusion in plagioclase, quartz and sanidine) analyses of samples from
several arc systems ranging in eruptive volume from < 1 km³ to > 5,000 km³ to obtain
observational evidence for the thermal conditions of arc magma storage. In particular
we quantify the maximum amount of time a given crystal could have resided in a
mobile magma (< 50% crystals, i.e., below the rheological lockup). This study is split
into two parts, the first is focused on the large, caldera-forming eruptions (≥ 10 km³)
and the second on the smaller, more typical arc eruptions (≤ 13 km³). Diffusion
timescales from 11 caldera-forming eruption reveal three types of magmatic systems:
1) relatively small volume systems (< ~100 km³) that record short residence times (<
~1200 years) at or above the rheological lockup temperature, 2) large volume systems
(> ~100 km³) that record long residence times (< 160,000 years) for plagioclase
diffusion and short timescales for quartz and sanidine, and 3) large volume systems
that record variable to low residence times. This suggests that the smaller systems
experience cold storage conditions where rejuvenation is needed to remobilized
magma that is locked up as a crystal mush. The longer residence times for the larger
systems suggests that thermal conditioning of the crust and/or higher magma fluxes
allow these magmas to be stored at elevated temperatures longer than the smaller
systems.
The second part of the study of the storage conditions of arc magmas gives
evidence for two different storage conditions. The smaller (<13 km³), more typical
arc magmatic systems all record short residence times (10¹-10³ years) at hightemperatures.
However these timescales are the result of two different processes. The
first is observed in the relatively crystal-poor systems (<20% crystals), where
diffusion records the timing of crystal growth after silicic melt extraction from crystal
mushes. The second process, recorded in crystal-rich systems (25-50% crystals),
suggests that they are stored as relatively cold crystal mushes that must be rapidly
remobilized prior to eruption. We conclude that the majority of these systems were
stored at low temperatures for much of their lifetimes.
Genre Thesis/Dissertation
Access Condition http://creativecommons.org/licenses/by-nc-nd/3.0/us/
Topic Magma
Identifier http://hdl.handle.net/1957/60340

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