Record Details

Empirical algorithms to estimate water column pH in the Southern Ocean

ScholarsArchive at Oregon State University

Field Value
Title Empirical algorithms to estimate water column pH in the Southern Ocean
Names Williams, N. L. (creator)
Juranek, L. W. (creator)
Johnson, K. S. (creator)
Feely, R. A. (creator)
Riser, S. C. (creator)
Talley, L. D. (creator)
Russell, J. L. (creator)
Sarmiento, J. L. (creator)
Wanninkhof, R. (creator)
Date Issued 2016-04-16 (iso8601)
Note To the best of our knowledge, one or more authors of this paper were federal employees when contributing to this work. This is the publisher’s final pdf. The article is copyrighted by the American Geophysical Union and published by Joh Wiley & Sons, Inc. It can be found at: http://agupubs.onlinelibrary.wiley.com/agu/journal/10.1002/%28ISSN%291944-8007/
Abstract Empirical algorithms are developed using high-quality GO-SHIP hydrographic measurements of commonly measured parameters (temperature, salinity, pressure, nitrate, and oxygen) that estimate pH in the Pacific sector of the Southern Ocean. The coefficients of determination, R² , are 0.98 for pH from nitrate (pH^N) and 0.97 for pH from oxygen (pH^Ox) with RMS errors of 0.010 and 0.008, respectively. These algorithms are applied to Southern Ocean Carbon and Climate Observations and Modeling (SOCCOM) biogeochemical profiling floats, which include novel sensors (pH, nitrate, oxygen, fluorescence, and backscatter). These algorithms are used to estimate pH on floats with no pH sensors and to validate and adjust pH sensor data from floats with pH sensors. The adjusted float data provide, for the first time, seasonal cycles in surface pH on weekly resolution that range from 0.05 to 0.08 on weekly resolution for the Pacific sector of the Southern Ocean.
Genre Article
Identifier Williams, N. L., Juranek, L. W., Johnson, K. S., Feely, R. A., Riser, S. C., Talley, L. D., ... & Wanninkhof, R. (2016). Empirical algorithms to estimate water column pH in the Southern Ocean. Geophysical Research Letters, 43(7), 3415-3422. doi:10.1002/2016GL068539

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