Record Details
Contrasting ion-association behaviour of Ta and Nb polyoxometalates
ScholarsArchive at Oregon State University
| Field | Value |
|---|---|
| Title | Contrasting ion-association behaviour of Ta and Nb polyoxometalates |
| Names |
Fullmer, Lauren B.
(creator) Molina, Pedro I. (creator) Antonio, Mark R. (creator) Nyman, May (creator) |
| Date Issued | 2014-11-07 (iso8601) |
| Note | To the best of our knowledge, one or more authors of this paper were federal employees when contributing to this work. This is the publisher’s final pdf. The published article is copyrighted by the Royal Society of Chemistry and can be found at: http://pubs.rsc.org/en/journals/journalissues/dt#!recentarticles&all. |
| Abstract | Small-angle X-ray scattering (SAXS) studies of aqueous [Ta₆O₁₉]⁸⁻ compared to prior studies of aqueous [Nb₆O₁₉]⁸⁻ reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb₆O₁₉]⁸⁻ and its counterions, solvent-separated ion-pairing between [Ta₆O₁₉]⁸⁻ and its counterions has been unveiled in the current study. |
| Genre | Article |
| Identifier | Fullmer, L. B., Molina, P. I., Antonio, M. R., & Nyman, M. (2014). Contrasting ion-association behaviour of Ta and Nb polyoxometalates. Dalton Transactions, 43(41), 15295-15299. doi:10.1039/C4DT02394C |
