Record Details

A Hybrid Redox-Supercapacitor System with Anionic Catholyte and Cationic Anolyte

ScholarsArchive at Oregon State University

Field Value
Title A Hybrid Redox-Supercapacitor System with Anionic Catholyte and Cationic Anolyte
Names Wang, B. (creator)
Maciá-Agulló, J. A. (creator)
Prendiville, D. G. (creator)
Zheng, X. (creator)
Liu, D. (creator)
Zhang, Y. (creator)
Boettcher, S. W. (creator)
Ji, X. (creator)
Stucky, G. D. (creator)
Date Issued 2014-05-09 (iso8601)
Note This is the publisher’s final pdf. The published article is copyrighted by the Electrochemical Society and can be found at: http://jes.ecsdl.org/.
Abstract A significant challenge for energy storage technologies is to realize battery-level energy density and capacitor-level durability and
power density in one device. By introducing an electrolyte composed of an anionic catholyte and a cationic anolyte into a symmetric
carbon-based supercapacitor configuration, a hybrid electrochemical battery-supercapacitor system using soluble redox species
delivers significantly improved energy density from 20 to 42 W•h/kg (based on the electrode mass) and stable capacities for > 10⁴
cycles. The ionic species formed in the electrolyte are studied by UV-Vis, Raman and mass spectroscopy to probe the energy storage
mechanism. The strategy is general and may provide a route to critically-needed fast-charging devices with both high energy density
and power.
Genre Article
Topic Energy storage
Identifier Wang, B., Maciá-Agulló, J. A., Prendiville, D. G., Zheng, X., Liu, D., Zhang, Y., ... & Stucky, G. D. (2014). A Hybrid Redox-Supercapacitor System with Anionic Catholyte and Cationic Anolyte. Journal of the Electrochemical Society, 161(6), A1090-A1093. doi:10.1149/2.058406jes

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