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Solution based prompt inorganic condensation and atomic layer deposition of Al₂O₃ films: A side-by-side comparison

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Field Value
Title Solution based prompt inorganic condensation and atomic layer deposition of Al₂O₃ films: A side-by-side comparison
Names Smith, Sean W. (creator)
Wang, Wei (creator)
Keszler, Douglas A. (creator)
Conley, John F., Jr. (creator)
Date Issued 2014-05-07 (iso8601)
Note This is the publisher’s final pdf. The published article is copyrighted by the American Vacuum Society and can be found at: http://scitation.aip.org/content/avs/journal/jvsta.
Abstract A comparison was made of Al₂O₃ films deposited on Si via prompt inorganic condensation (PIC)
and atomic layer deposition (ALD). Current–voltage measurements as a function of annealing
temperature indicate that the solution-processed PIC films, annealed at 500°C, exhibit lower
leakage and roughly equivalent breakdown strength in comparison to ALD films. PIC films are
less dense than as-deposited ALD films and capacitance–voltage measurements indicate a lower
relative dielectric constant. On the basis of x-ray photoelectron spectroscopy, transmission
electron microscopy, and energy dispersive x-ray spectroscopy, it is found that the 500°C anneal
results in the formation of a ~6 nm thick interfacial SiO₂ layer at the Si interface. This SiO₂
interfacial layer significantly affects the electrical performance of PIC Al₂O₃ films deposited on
Si.
Genre Article
Identifier Smith, S. W., Wang, W., Keszler, D. A., & Conley Jr, J. F. (2014). Solution based prompt inorganic condensation and atomic layer deposition of Al₂O₃ films: A side-by-side comparison. Journal of Vacuum Science & Technology A, 32(4), 041501. doi:10.1116/1.4874806

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