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A new multisource and high-frequency approach to measuring δ²H and δ¹⁸O in hydrological field studies

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Title A new multisource and high-frequency approach to measuring δ²H and δ¹⁸O in hydrological field studies
Names Pangle, Luke A. (creator)
Klaus, Julian (creator)
Berman, Elena S. F. (creator)
Gupta, Manish (creator)
McDonnell, Jeffrey J. (creator)
Date Issued 2013-11-20 (iso8601)
Note This is the publisher’s final pdf. The published article is copyrighted by American Geophysical Union and can be found at: http://onlinelibrary.wiley.com/journal/10.1002/%28ISSN%291944-7973.
Abstract Measurements of δ²H and δ¹⁸O in isotope-based field studies have fundamentally
improved our understanding of water flow and transport time scales in soils and headwater
catchments. Until recently, however, technical constraints have limited the temporal
resolution at which water samples could be collected and analyzed. We introduce a new
sample acquisition system—consisting of a four-channel peristaltic pump, custom flow
manifold, and CTC LCPAL auto-sampler—that is paired with a field-deployable laser
spectrometer (LGR LWIA). Our system enables high-frequency (subhourly) measurement
of δ²H and δ¹⁸O in as many as four water sources. We deployed the system at a field site in
Corvallis, OR, USA, where we measured the δ²H and δ¹⁸O composition of precipitation and
the drainage from two lysimeters. The system produced δ²H and δ¹⁸O time series for
precipitation and drainage from each lysimeter at a temporal frequency of one sample every
34 min, which, on average, corresponded to 0.84, 0.63, and 0.48 mm of precipitation or
lysimeter drainage per sample. The high-frequency data showed substantially greater short-term
variability than observed when sampling at successively longer time intervals. The
system and sampling configuration are versatile and can be adapted to sample multiple
water flows at variable frequencies depending on the characteristic transit times of each
source.
Genre Article
Topic Stable isotopes
Identifier Pangle, L. A., J. Klaus, E. S. F. Berman, M. Gupta, and J. J. McDonnell (2013), A new multisource and high-frequency approach to measuring δ²H and δ¹⁸O in hydrological field studies, Water Resources Research, 49, 7797–7803. doi:10.1002/2013WR013743

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