Record Details
Synthesis of some bicyclo[6.1.0] - nonane derivatives
ScholarsArchive at Oregon State University
| Field | Value |
|---|---|
| Title | Synthesis of some bicyclo[6.1.0] - nonane derivatives |
| Names |
Wall, Robert Gene
(creator) Marvell, Elliot N. (advisor) |
| Date Issued | 1963-05-29 (iso8601) |
| Note | Graduation date: 1964 |
| Abstract | Bicyclo [6.1.0] non-4-ene was prepared by two routes; (1) reaction of cis-cis-1, 5-cycloöctadiene with methylene iodide and zinc-copper couple, (2) sodium-methanol reduction of 9, 9-dibromobicyclo-[6.1.0] non-4-ene. The bicyclononene was characterized by its infrared spectrum, nuclear magnetic resonance spectrum and common physical properties. The olefin was hydrogenated to bicyclo [6.1.0] - nonane. 9, 9- Dibromobicyclo [6.1.0] non-4-ene was prepared by dibromocarbene addition to 1, 5-cycloöctadiene. Structure proof was provided by the analytical results, infrared spectrum, nuclear magnetic resonance spectrum and the conversion to bicyclo [6.1.0] non-4-ene. The acetolysis of bicyclo [6.1.0] non-4-ene was carried out and the products analyzed by vapor phase chromatography. At least eight major products were indicated. |
| Genre | Thesis/Dissertation |
| Topic | Bicyclic compounds |
| Identifier | http://hdl.handle.net/1957/48763 |
