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Water uptake in biochars: The roles of porosity and hydrophobicity

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Title Water uptake in biochars: The roles of porosity and hydrophobicity
Names Gray, Myles (creator)
Johnson, Mark G. (creator)
Dragila, Maria I. (creator)
Kleber, Markus (creator)
Date Issued 2014-02 (iso8601)
Note To the best of our knowledge, one or more authors of this paper were federal employees when contributing to this work. This is the publisher’s final pdf. The published article is copyrighted by Elsevier and can be found at: http://www.journals.elsevier.com/biomass-and-bioenergy/.
Abstract We assessed the effects of porosity and hydrophobicity on water uptake by biochars.
Biochars were produced from two feedstocks (hazelnut shells and Douglas fir chips) at
three production temperatures (370°C, 500°C, and 620°C). To distinguish the effects of
porosity from the effects of hydrophobicity, we compared uptake of water to uptake of
ethanol (which is completely wetting and not affected by hydrophobic materials). For both
feedstocks, low temperature biochars took up less water than high temperature biochars
but the same amount of ethanol, suggesting that differences in water uptake based on
production temperature reflect differences in surface hydrophobicity, not porosity.
Conversely, Douglas fir biochars took up more water than hazelnut shell biochars due to
greater porosity. Thus, designing biochars for water holding applications requires two
considerations: (a) creating sufficient porosity through feedstock selection, and (b) determining
a production temperature that reduces hydrophobicity to an acceptable level.
Genre Article
Topic Biochar
Identifier Gray, M., Johnson, M. G., Dragila, M. I., & Kleber, M. (2014). Water uptake in biochars: The roles of porosity and hydrophobicity. Biomass and Bioenergy, 61, 196-205. doi:10.1016/j.biombioe.2013.12.010

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