Record Details

Condensation reactions of certain aldehydes and amines with acetylbenzoyl

ScholarsArchive at Oregon State University

Field Value
Title Condensation reactions of certain aldehydes and amines with acetylbenzoyl
Names Klemm, Waldemar Arthur, Jr. (creator)
Logan, A. V. (advisor)
Date Issued 1967-05-05 (iso8601)
Note Graduation date: 1967
Abstract Acetylbenzoyl reacted with dimethylamine hydrochloride
and benzaldehyde in primary isoamyl alcohol under
reflux conditions to form 1,4-diphenvl-3-butene-1,2-dione,
compound I, which melted at 56-57°C.
Compound I formed a quinoxaline derivative, compound
II, which melted at 152.5-153°C.
Compound I was cleaved by hydrogen peroxide to form
cinnamic acid, compound III, which melted at 133°C.
Acetylbenzoyl reacted with dimethylamine hydrochloride
and benzaldehyde in glacial acetic acid under
reflux conditions to form 1,4,5-tripheny-1,2,5-pentanetrione,
compound IV, which melted at 192-193°C,
Compound IV formed an oxime derivative, compound V,
which melted at 232-233°C.
Genre Thesis/Dissertation
Topic Acetylbenzoyl
Identifier http://hdl.handle.net/1957/47467

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