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The relationship of exchange acidity and exchangeable aluminum in limed and unlimed profile samples of soil from western Oregon to the yield and chemical composition of alfalfa

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Title The relationship of exchange acidity and exchangeable aluminum in limed and unlimed profile samples of soil from western Oregon to the yield and chemical composition of alfalfa
Names Janghorbani, Morteza (creator)
Roberts, Steve (advisor)
Date Issued 1968-08-01 (iso8601)
Note Graduation date: 1969
Abstract Acidity distribution within any given soil profile is dependent on
mineralogical make-up of the parent material as well as environmental conditions prevalent during the weathering history of the soil.
An experiment was designed to study the distribution pattern of exchange acidity, exchangeable aluminum, exchangeable manganese and
pH of six acid soils of Western Oregon. 1N KCl extracts of four
depths of each soil were obtained and the levels of the parameters
mentioned above were measured. It was found that various soil series
had different acidity distribution patterns within their profiles. Also,
a highly significant linear correlation was observed between exchange
acidity and exchangeable aluminum of each soil.
Liming acid soils raises pH of the soil extract and improves
its fertility status. The rise in pH is due to neutralization of acid
groups or acid-producing species present in various forms and on
various sites in the soil system. One group of these acid producing
species is the exchangeable form of various hydrolyzable cations, especially Al⁺³, H₃O⁺, Mn⁺², also perhaps Fe⁺³, and others. These
cations are extracted with solutions of 1N neutral salts such as KC1
and are neutralized by hydroxyls of the applied lime. A second experiment was designed to study the effect of liming, using an incubation procedure, on exchange acidity, exchangeable aluminum, exchangeable manganese and pH of these soils. It was observed that
additions of increments of Ca(OH)₂ to soil resulted in progressive
increase in pH of the soil extract and the relationship between pH and
amounts of lime applied was curvilinear with the titration curves
approximating linear patterns. As lime rates increase, there was a drop in both Al⁺³ and exchange acidity content of the soil extract as
well as the amount of Mn⁺² extracted. For all these three parameters the initial drop was much sharper than the subsequent reductions occurring due to further additions of lime. Point of zero acidity
or zero exchangeable aluminum did not necessarily coincide with pH
of neutrality.
Applications of lime to acid soils improves their crop raising
ability, especially with regard to legumes. A third experiment was set up to study the response pattern of alfalfa (Medicago sativa L.
var. Du Puits) to lime and phosphorous applications and the effect of
such applications on aluminum, manganese, phosphorous, and
calcium concentrations of plant tops. Significant yield responses
were obtained in some cases but not in others. Phosphorous concentration of the tops was not significantly affected, but aluminum,
manganese, and calcium concentrations were affected to varying
degrees.
Genre Thesis/Dissertation
Topic Soils -- Oregon
Identifier http://hdl.handle.net/1957/47278

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