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Factors influencing the herbicidal activity and persistence of isomers of 1, 1-dimethyl-diisopropyl-indanyl ethyl ketone in soil

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Title Factors influencing the herbicidal activity and persistence of isomers of 1, 1-dimethyl-diisopropyl-indanyl ethyl ketone in soil
Names Donaldson, Dean Robert (creator)
Appleby, Arnold P. (advisor)
Date Issued 1967-10-06 (iso8601)
Note Graduation date: 1968
Abstract The purpose of this study was to evaluate the activity of Sindone
(isomers of 1, 1-dimethyl-diisopropyl-indanyl ethyl ketone) under
field conditions and to gain information regarding the rate of detoxification
of Sindone in soil. A series of trials were established in
sugar beet fields in California, Oregon, and Washington. Sindone
was applied as a pre-plant treatment, power incorporated to a
depth of 1.5 inches, at rates of 0, 1.5, and 3.0 lb /A active ingredient,
and followed by sprinkler or furrow irrigation. The toxicity of
Sindone to emerging sugar beets and seedling grasses was recorded.
Yield data were collected where possible. Incorporated Sindone
gave good grass control at rates of 1.5 to 3.0 lb /A when irrigated
after application. Areas that received no irrigation within four
weeks after application showed no visible weed control. Rates of Sindone that gave good grass control injured sugar beets.
A series of greenhouse experiments were conducted to study
the detoxification rate of Sindone in soil. The rate of detoxification
was determined at soil moisture levels of 47%, 77%, and 102% field
capacity. Treated soils were stored at -18, +5, +25, and +35°C.
Barnyardgrass (E. crusgalli) was used as the bioassay species.
The rate of detoxification was greatest at the 77% moisture
level and at 35°C. Sindone degradation rates were also determined
in eight agricultural soil types stored at +25°C. The rate of detoxification
indicated a half-life for incorporated Sindone under these
conditions of approximately six months.
The results of this study indicate that Sindone offers little
promise as a sugar beet herbicide because of lack of selectivity.
However, the long half-life indicates potential usage in perennial
crops or in turf weed control. Bioassay results indicate a strong
possibility that phytotoxic metabolites are formed in the degradation
process.
Genre Thesis/Dissertation
Topic Herbicides
Identifier http://hdl.handle.net/1957/47180

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