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Influence of soil moisture on movement of terbacil in soil

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Title Influence of soil moisture on movement of terbacil in soil
Names Vesecky, John Francis (creator)
Appleby, Arnold P. (advisor)
Date Issued 1968-07-22 (iso8601)
Note Graduation date: 1969
Abstract Previous field research with terbacil (3-tert-butyl-5-chloro-
6-methyluracil) has shown that early fall applications to dry soil
performed better than did late fall or early winter applications to
wet soil. Field and greenhouse studies were conducted to determine
the effect of soil moisture content at time of application and the
effect of moisture applied after herbicide application on the leaching
of terbacil.
A field trial was initiated during the summer in which terbacil
was applied to saturated and dry soil and allowed to dry one week
before sprinkler irrigation. Terbacil was also applied to saturated
and dry soil which was irrigated immediately. Three-and-one-half
inches of irrigation water were applied. Of the three test species,
rape (Brassica napus L.) was very sensitive, oats (Avena sativa L.)
was moderately sensitive, and corn (Zea mays L.) was relatively
tolerant to terbacil. The field bioassay showed that terbacil was the
least effective when applied to dry soil with a one-week interim
before irrigation. Herbicidal activity was noticeably better when
terbacil was applied to wet soil or to dry soil if irrigated
immediately. Bioassays of core samples taken from the plots indicated
that terbacil sprayed on dry soil one week before irrigation was the
least subject to leaching. Terbacil applied to dry soil and irrigated
immediately appeared to leach the greatest distance.
Leaching studies in the greenhouse were conducted with soil
columns consisting of two layers of soil. The bottom nine-inch layer
was saturated and the top two-inch layer, to which terbacil was
applied, was either saturated or air dry. Ten inches of water were
added immediately, three days, and seven days after application of the
herbicide. Bioassay tests showed that terbacil leached the greatest
distance when water was applied immediately. When water was applied
seven days after terbacil applications, slightly greater leaching of
terbacil occurred when applied to wet soil than to dry soil. Analysis
of the leachates by gas-liquid chromatography showed that less terbacil
was leached through columns in which water was applied three days
after application compared to those receiving water immediately after
application. However, the speed with which water moved through the
columns was quite variable.
Analysis of leachates from soil columns in which the entire
soil mass was at one moisture level, saturated or air dry, showed that
more terbacil leached through the wet soil than the dry soil when ten
inches of water was applied. Again, less terbacil was found in the
leachates from columns leached three days after terbacil application
compared to those leached immediately. Core samples were taken in April from a field trial in which
terbacil had been applied in October and December. The October
treatments had given excellent control of winter-germinating weeds
while the December treatments failed to give satisfactory control at
any rate. Bioassays of the core samples showed no marked differences
in depth of leaching of the terbacil from the two dates of application.
These results would indicate that the large differences in weed control
that have consistently been observed between early fall and winter applications
of terbacil are not due to differences in depth of leaching.
Genre Thesis/Dissertation
Topic Herbicides -- Testing
Identifier http://hdl.handle.net/1957/46476

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