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Symmetry allowed charge-transfer transitions between spin-orbit states in the gaseous dihalides of Mn, Co, Ni, and Cu

ScholarsArchive at Oregon State University

Field Value
Title Symmetry allowed charge-transfer transitions between spin-orbit states in the gaseous dihalides of Mn, Co, Ni, and Cu
Names Konopka, Ronald Francis (creator)
DeKock, C. W. (advisor)
Date Issued 1969-06-16 (iso8601)
Note Graduation date: 1970
Abstract The spin-orbit states of both the ground and several
charge-transfer-excited electronic configurations of
gaseous MnX₂, CoX₂, NiX₂, and CuX₂ are derived. Only one-electron
transitions from the ground electronic state are
considered. The molecules are treated as linear in both
the ground and excited states. In each case, the spin-orbit
states of the excited configurations are components
of zero-order terms with the same multiplicity as the
ground state zero-order term. The symmetry allowed,
electric dipole excited, spin-orbit states are found for
each molecule. Polarization properties of transitions to
these states are also considered. The transitions expected
for each gaseous molecule and the information obtained
from symmetry and polarization studies are
discussed.
Genre Thesis/Dissertation
Topic Halides
Identifier http://hdl.handle.net/1957/46297

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