Record Details

Hydro-biogeochemical coupling at the hillslope and catchment scale

ScholarsArchive at Oregon State University

Field Value
Title Hydro-biogeochemical coupling at the hillslope and catchment scale
Names van Verseveld, W.J. (Willem J.) (creator)
McDonnell, Jeffrey J. (advisor)
Date Issued 2007-10-01T17:32:23Z (iso8601)
Internet Media Type application/pdf
Note Graduation date: 2008
Abstract The specific objectives of this dissertation are to determine subsurface flow
behaviors across different antecedent wetness conditions from a top-down perspective
and to mechanistically assess the hydrological controls on DOC and N transport at the
hillslope and catchment scale. The study area is a small catchment where hillslopes
issue directly to the stream witho ut any riparian zone modulation. Subsurface flow is
measured from a 10 m wide trench. Streamflow is measured at the catchment outlet.
Tree regression of subsurface flow and soil matric potential with controlling variables
rainfall history and antecedent wetness show three different subsurface flow
behaviors. Furthermore, unsaturated zone dynamics that follow the Darcy-Richard’s
equation are a dominant control on rainfall pulse propagation. DOC and DON
concentrations in subsurface flow and in stream water decrease from the transition
(Fall) period to the wet (Winter-Spring) period, suggesting supply-limited DOC and
DON at the seasonal scale. Specific UV absorbance (SUVA), a tool to “fingerprint”
sources, is always lower in subsurface flow compared to stream water, suggesting
transient groundwater (high SUVA) mixes differently with seepage groundwater (low
SUVA) at the hillslope and catchment scale, even when subsurface flow and stream
water are ‘in sync’ with respect to DOC and N during the wet period. The dominant
flushing mechanism at the hillslope and catchment scale is vertical transport of
nutrients, by ‘preferential flow’ to the soil-bedrock interface and then laterally
downslope with limited supply of nutrients in the organic horizon, and higher
contributions of deep soil water/seepage groundwater during the falling limb
compared to the rising limb of the hydrograph. Two dominant flowpaths: vertical flow
and then lateral along the soil-bedrock interface, mass transfer between a small mobile
zone and a large immobile zone, and dispersive mixing, in combination with supplylimited
DOC in the organic horizon/shallow layer lead to a conceptual model that
resolves the double paradox: rapid mobilization of old water but variable runoff
chemistry. Overall these findings result in a mechanistically plausible conceptual
model how DOC and N are transported at the hillslope and catchment scale.
Genre Thesis
Topic catchment hydrology
Identifier http://hdl.handle.net/1957/6605

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