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Past Methane Release Events and Environmental Conditions at the Upper Continental Slope of the South China Sea: Constraints by Seep Carbonates

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Title Past Methane Release Events and Environmental Conditions at the Upper Continental Slope of the South China Sea: Constraints by Seep Carbonates
Names Han, Xiqiu (creator)
Suess, Erwin (creator)
Liebetrau, Volker (creator)
Eisenhauer, Anton (creator)
Huang, Yongyang (creator)
Date Issued 2014-10 (iso8601)
Note This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Springer and can be found at: http://www.springer.com/earth+sciences+and+geography/geology/journal/531
Abstract Authigenic carbonates and chemosymbiotic biota are archives of seepage 1 history and record paleo-environmental conditions at seep sites. Based on mineral and stable isotope compositions and U/Th-isotope
systematics of seep carbonates and Calyptogena sp shell fragments from three seep sites located at 22°02' ~22°09'N,
118°43'~118°52'E (water depths: 473 m to 785 m) in the northeastern slope of the South China Sea, we obtained the
timing of past methane release events and identified samples formed in contact with bottom seawater with negligible
pore water influence, largely aragonitic chemoherm samples and shells, to reconstruct the palaeo-bottom water
temperatures during their formation. Our results show that all methane release events occurred between 11.5±0.2 ka
and 144.5±12.7 ka, when sea-levels were about 62 m to 104 m lower than today. The enhanced methane release
during low sea-level stands is thought to be a modulating on reduced hydrostatic pressure, increased incision of
canyons and the increase of sediment loading. The calculated past bottom water temperatures at one site (Site 3;
water depth: 767 m to 771 m) during the periods of low sea-level stands between 11.5 ka and 65 ka were in the range
of ~3.3 °C to ~4.0 °C, that is ~1.3 °C to ~2.2 °C colder than at present. The reliability of δ¹⁸O of seep carbonates and
vent bivalve shells as a proxy for bottom water temperatures is critically assessed in light of seepage ¹⁸O-enriched
fluids from gas hydrate and/or clay dehydration water. Our approach provides for the first time an independent
estimate of past bottom water temperatures of the upper continental slope of the South China Sea.
Genre Article
Topic Seep carbonates
Identifier Han, X., E. Suess, V. Liebetrau, A. Eisenhauer, Y. Huang 2014. Past methane release events and environmental conditions at the upper continental slope of the South China Sea: constraints by seep carbonates. Int J Earth Sci (Geol Rundsch) (2014) 103:1873–1887; DOI 10.1007/s00531-014-1018-5

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