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High-resolution glacial and deglacial record of atmospheric methane by continuous-flow and laser spectrometer analysis along the NEEM ice core

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Title High-resolution glacial and deglacial record of atmospheric methane by continuous-flow and laser spectrometer analysis along the NEEM ice core
Names Chappellaz, J. (creator)
Stowasser, C. (creator)
Blunier, T. (creator)
Baslev-Clausen, D. (creator)
Brook, Edward J. (creator)
Dallmayr, R. (creator)
Fain, X. (creator)
Lee, J. E. (creator)
Mitchell, L. E. (creator)
Pascual, O. (creator)
Romanini, D. (creator)
Rosen, J. (creator)
Schuepbach, S. (creator)
Date Issued 2013 (iso8601)
Note This is the publisher’s final pdf. The published article is copyrighted by the author(s) and published by Copernicus Publications on behalf of the European Geosciences Union. The published article can be found at: http://www.clim-past.net/volumes_and_issues.html.
Abstract The Greenland NEEM (North Greenland Eemian
Ice Drilling) operation in 2010 provided the first opportunity
to combine trace-gas measurements by laser spectroscopic
instruments and continuous-flow analysis along a
freshly drilled ice core in a field-based setting. We present
the resulting atmospheric methane (CH₄) record covering
the time period from 107.7 to 9.5 ka b2k (thousand years
before 2000 AD). Companion discrete CH₄ measurements
are required to transfer the laser spectroscopic data from a
relative to an absolute scale. However, even on a relative
scale, the high-resolution CH₄ data set significantly improves
our knowledge of past atmospheric methane concentration
changes. New significant sub-millennial-scale features appear
during interstadials and stadials, generally associated
with similar changes in water isotopic ratios of the ice, a
proxy for local temperature. In addition to the midpoint of
Dansgaard–Oeschger (D/O) CH₄ transitions usually used for
cross-dating, sharp definition of the start and end of these
events brings precise depth markers (with ±20 cm uncertainty)
for further cross-dating with other palaeo- or ice core
records, e.g. speleothems. The method also provides an estimate
of CH₄ rates of change. The onsets of D/O events in the methane signal show a more rapid rate of change
than their endings. The rate of CH₄ increase associated with
the onsets of D/O events progressively declines from 1.7 to
0.6 ppbv yr⁻¹ in the course of marine isotope stage 3. The
largest observed rate of increase takes place at the onset of
D/O event #21 and reaches 2.5 ppbv yr⁻¹.
Genre Article
Access Condition http://creativecommons.org/licenses/by/3.0/us/
Identifier Chappellaz, J., Stowasser, C., Blunier, T., Baslev-Clausen, D., Brook, E. J., Dallmayr, R., Faïn, X., Lee, J. E., Mitchell, L. E., Pascual, O., Romanini, D., Rosen, J., and Schüpbach, S.: High-resolution glacial and deglacial record of atmospheric methane by continuous-flow and laser spectrometer analysis along the NEEM ice core, Climate of the Past, 9, 2579-2593, doi:10.5194/cp-9-2579-2013, 2013.

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