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Eolian transport of glycerol dialkyl glycerol tetraethers (GDGTs) off northwest Africa

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Title Eolian transport of glycerol dialkyl glycerol tetraethers (GDGTs) off northwest Africa
Names Fietz, Susanne (creator)
Prahl, Fredrick G. (creator)
Moraleda, Nuria (creator)
Rosell-Mele, Antoni (creator)
Date Issued 2013-11 (iso8601)
Note This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Elsevier and can be found at: http://www.journals.elsevier.com/organic-geochemistry/.
Abstract Branched glycerol dialkyl glycerol tetraethers (brGDGTs) of purportedly terrestrial
origin are frequently detected in marine sediments, even in remote ocean sites where no
direct impact from land erosion via rivers takes place. At these places, the most likely
explanation for the presence of brGDGTs is in situ production or eolian transport, but
neither possibility has been demonstrated in the open ocean. Here, we report the presence
of isoprenoid (iso) and brGDGTs in eight dust samples collected off Northwest Africa.
Based on previous studies, prevailing wind patterns, bulk chemistry, n-alkane
composition and isotopic signatures, we show that Northwest Africa is the likely
principal origin of the GDGTs in the dust. The concentrations of plant wax n-alkanes in
the dust are several orders of magnitudes higher than those of GDGTs, and, based on the
distributions of these two compound classes, we infer that they tag different carbon pools
and sources of organic matter. Our finding demonstrates that brGDGTs and isoGDGTs in
marine sediments and wind-derived deposits can have an eolian source. Consequently,
climate reconstruction may be attempted from wind-derived deposits of brGDGTs, even
in remote oceanic areas.
Genre Article
Topic allochthonous input
Identifier Fietz, S., Prahl, F. G., Moraleda, N., & Rosell-Melé, A. (2013). Eolian transport of glycerol dialkyl glycerol tetraethers (GDGTs) off Northwest Africa. Organic Geochemistry, 64, 112-118. doi:10.1016/j.orggeochem.2013.09.009

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