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Seawater intrusion through the oceanic crust and carbonate sediment in the Equatorial Pacific: Lithium abundance and isotopic evidence

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Title Seawater intrusion through the oceanic crust and carbonate sediment in the Equatorial Pacific: Lithium abundance and isotopic evidence
Names You, Chen-Feng (creator)
Chan, L.-H. (creator)
Gieskes, J. M. (creator)
Klinkhammer, Gary P. (creator)
Date Issued 2003-11-13 (iso8601)
Note Copyrighted by American Geophysical Union.
Abstract Large-scale lateral advection of seawater within the
oceanic crust is thought to be the cause of low heat flow in
the Equatorial Pacific. Until now supportive evidence is
limited to reversals of B and δ¹¹B, Ca, Mg, SO₄⁻², Sr and
⁸⁷Sr/⁸⁶Sr in sediment pore waters. Here we report new
evidence from a detailed study of Li and its isotopes in
sediment cores from ODP Sites 844 and 851. Carbonates at
these sites were significantly recrystallized leading to large
variations in Li and δ⁷Li in the sediments and associated
pore waters. In addition to diagenetic effects, distinct
reversals in lithium concentration and isotopic ratio toward
modern seawater composition are observed in waters near
the basaltic basement, lending further support to the
seawater intrusion hypothesis. Three endmembers are
identified in the pore waters: seawater, a diagenetically
altered component, and evolved crustal fluid. The new
lithium isotopic results underscore the importance of
diagenetic artifacts in carbonate sediments.
Genre Article
Topic Li isotopes
Identifier You, C.-F., L.-H. Chan, J. M. Gieskes, and G. P. Klinkhammer, Seawater intrusion through the oceanic crust and carbonate sediment in the Equatorial Pacific: Lithium abundance and isotopic evidence, Geophys. Res. Lett., 30(21), 2120, 2003.

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